Fiber Innovations: From Production to Application > Textile Processing & Application

Liquid Crystal Elastomer Fibers for Application in Soft Robotics and Medical Technology

Saal C
Donnerstag, 11.09.2025, 09:00 - 09:20 Uhr

Liquid crystal elastomers (LCE) are an emerging material class known for their ability to reversibly contract and perform work with great potential to replace electromotoric-driven motion, e.g. in medical technology (prostethics) or robotics. Currently LCE are mainly fabricated as thin films, limiting their potential applications. A new wet spinning method to generate LCE fibers will be presented and resulting contractile fibers are characterized and compared with LCE film, shape memory polymers, as well as human muscle.

Sprecher
Lukas Benecke (Institute of Textile Machinery and High Performance Material Technology, TU Dresden)
Co-Authoren
Dilbar Aibibu (Institute of Textile Machinery and High Performance Material Technology, TU Dresden), Chokri Cherif (Institute of Textile Machinery and High Performance Material Technology, TU Dresden)
LCEF were prepared via hydrosilation of the elastomer PMHS and liquid crystal (LC) MBB using a mixture of 11UB and vinyl-terminated PDMS as crosslinks. During wet spinning, a heated oil bath was used to initiate the first thermal crosslinking step to achieve fiber shape stability. Fibers were then drawn with a ratio of max. 2.3. Shear stress during this process was used to align the LC, generating an anisotropic state. After drawing, a second thermal crosslinking step was applied to fixate LC orientation along the fiber axis. This orientation is required to achieve contractile behavior of the LCEF after surpassing nematic-isotropic transition temperature (TNI). At this temperature, LC are enabled to reorientate/ realign, aiming for a state of maximum entropy or perfect isotropy. The rotation of the LC is transferred onto the elastomeric backbone, in which polymer chains will therefore lose their stretched state, resulting in a macroscopic contraction of the fiber. The as spun LCEF were characterized regarding mechanical properties, contraction, and mass-specific power and compared to LCE-films, shape-memory polymers (SMP), SMP-fibers, as well as human muscle. Results show great potential of these LCE fibers for application in medicine and soft robotics.